Structural, Spectroscopic and Magnetic Properties of [Cu(1-meim)(4)]center dot 2(PF6)

Yildirim I., Karabulut B.

9th International Physics Conference of the Balkan-Physical-Union (BPU), İstanbul, Turkey, 24 - 27 August 2015, vol.1722 identifier identifier

  • Publication Type: Conference Paper / Full Text
  • Volume: 1722
  • Doi Number: 10.1063/1.4944152
  • City: İstanbul
  • Country: Turkey
  • Ondokuz Mayıs University Affiliated: Yes


[Cu(1-meim)(4)]center dot 2(PF6) (1-meim: 1-methylimidazole) complex has been synthesized and characterized by EPR, FT-IR, and XRD techniques. The Cu(II) complex crystallizes in the monoclinic system with the space group P2(1)/c. EPR spectrum of [Cu(1-meim)(4)]center dot 2(PF6) powder has been studied at room temperature. The spin Hamiltonian parameters (g and hyperfine values) have been calculated. The results indicate the axial symmetry around the paramagnetic Cu2+ center. The ground state wave function of Cu2+ ion has been constructed. The unpaired electron spends most of its time in dx(2)-y(2) orbital.