Structural, Spectroscopic and Magnetic Properties of [Cu(1-meim)(4)]center dot 2(PF6)

Yildirim I., Karabulut B.

9th International Physics Conference of the Balkan-Physical-Union (BPU), İstanbul, Türkiye, 24 - 27 Ağustos 2015, cilt.1722, (Tam Metin Bildiri) identifier identifier

  • Yayın Türü: Bildiri / Tam Metin Bildiri
  • Cilt numarası: 1722
  • Doi Numarası: 10.1063/1.4944152
  • Basıldığı Şehir: İstanbul
  • Basıldığı Ülke: Türkiye
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

[Cu(1-meim)(4)]center dot 2(PF6) (1-meim: 1-methylimidazole) complex has been synthesized and characterized by EPR, FT-IR, and XRD techniques. The Cu(II) complex crystallizes in the monoclinic system with the space group P2(1)/c. EPR spectrum of [Cu(1-meim)(4)]center dot 2(PF6) powder has been studied at room temperature. The spin Hamiltonian parameters (g and hyperfine values) have been calculated. The results indicate the axial symmetry around the paramagnetic Cu2+ center. The ground state wave function of Cu2+ ion has been constructed. The unpaired electron spends most of its time in dx(2)-y(2) orbital.