The microwave-assisted synthesis and characterization of novel polymeric phthalocyanines containing resorcinarene

KANTAR C., Ağar E., ŞAŞMAZ S.

DYES AND PIGMENTS, cilt.77, sa.3, ss.487-492, 2008 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 77 Sayı: 3
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1016/j.dyepig.2007.07.017
  • Dergi Adı: DYES AND PIGMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.487-492
  • Anahtar Kelimeler: microwave-assisted, polymeric phthalocyanines, resorcinarene, SUBSTITUTED PHTHALOCYANINES, METALLOPHTHALOCYANINES, IRRADIATION, CAVITANDS, COMPLEXES, TRANSPORT, MOIETIES, SOLVENT
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

Novel metal phthalocyanine (Cu, Zn, Co, Ni) polymers containing resorcinarene moieties were prepared; the resorcinarene was obtained by the acid-catalysed cyclocondensation of resorcinol and acetalclehyde under microwave irradiation. The resorcinarene phthalonitrile compounds were then synthesized by treating resorcinarene with 4,5-dichloro-1,2-dicyanobenzene and 4-nitro-1,2-dicyanobenzene under microwave irradiation, respectively. Cu(II), Co(II) and Ni(H) chlorides were employed in order to synthesize the corresponding metal phthalocyanine polymers and Zn(CH3CO2) was used to prepare zinc phthalocyanine polymers. Structures were characterized by elemental analyses, H-1 NMR, C-13 NMR, UV-vis and FTIR spectroscopy. (c) 2007 Elsevier Ltd. All rights reserved.