Supramolecular lead(II) azide complex of 2,6-diacetylpyridine dihydrazone: synthesis, molecular structure, and biological activity

Kazak C., Arslan N. B., KARABULUT S., AZAZ A. D., NAMLI H., Kurtaran R.

JOURNAL OF COORDINATION CHEMISTRY, vol.62, no.18, pp.2966-2973, 2009 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 62 Issue: 18
  • Publication Date: 2009
  • Doi Number: 10.1080/00958970902980537
  • Journal Name: JOURNAL OF COORDINATION CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.2966-2973
  • Keywords: Biological activity, Schiff base, Dihydrazone, Lead complex, Azido bridge, X-RAY, LONE-PAIR, POLYMERS
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

The complex of 2,6-diacetylpyridinedihydrazone (L) with lead(II) and azide has been characterized by elemental analyses, FTIR, and single-crystal X-ray analysis. The Pb(C9H13N11) (1) crystallized in the monoclinic space group C2/c. The coordination of 1 exhibits a gap around the lead(II), possibly occupied by a stereochemically active electron lone pair on lead(II) resulting in a hemidirected complex. Antimicrobial activity of the complex is higher than the free ligand.