Supramolecular lead(II) azide complex of 2,6-diacetylpyridine dihydrazone: synthesis, molecular structure, and biological activity
JOURNAL OF COORDINATION CHEMISTRY, cilt.62, sa.18, ss.2966-2973, 2009 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 62 Sayı: 18
- Basım Tarihi: 2009
- Doi Numarası: 10.1080/00958970902980537
- Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.2966-2973
- Anahtar Kelimeler: Biological activity, Schiff base, Dihydrazone, Lead complex, Azido bridge, X-RAY, LONE-PAIR, POLYMERS
- Ondokuz Mayıs Üniversitesi Adresli: Evet
Özet
The complex of 2,6-diacetylpyridinedihydrazone (L) with lead(II) and azide has been characterized by elemental analyses, FTIR, and single-crystal X-ray analysis. The Pb(C9H13N11) (1) crystallized in the monoclinic space group C2/c. The coordination of 1 exhibits a gap around the lead(II), possibly occupied by a stereochemically active electron lone pair on lead(II) resulting in a hemidirected complex. Antimicrobial activity of the complex is higher than the free ligand.