Synthesis and spectroscopic characterization of four new substituted piperazineglyoximes and their complexes with some transition metals
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, cilt.28, sa.5, ss.833-841, 1998 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 28 Sayı: 5
- Basım Tarihi: 1998
- Doi Numarası: 10.1080/00945719809349385
- Dergi Adı: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.833-841
- Ondokuz Mayıs Üniversitesi Adresli: Evet
Özet
Four new substituted piperazineglyoximes, 4-methyl-1-piperazineglyoxime (MPGH2) 4-benzyl-1-piperazineglyoxime (BPGH2), 1,2-bis(4-methylpiperazine)glyoxime (BMPGH2) and 1,2-bis(4-benzylpiperazine)glyoxime (BBPGH2) have been synthesized by the reactions of anti-chloroglyoxime or dichloroglyoxime with substituted piperazines in ethanol. All these glyoximes are in the anti-form according to 1H NMR, 13C NMR and IR spectral data. The complexes of Cu(II), Co(II) and Ni(II) with these four glyoxime ligands have been prepared and characterized by using IR and UV-VIS spectral data and elemental analyses.