The influence of moisture on deprotonation mode of imidazolinium chlorides with palladacycle acetate dimer

Gunay M. E., Özdemir N., Ulusoy M., Ucak M., Dincer M., Cetinkaya B.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol.694, no.14, pp.2179-2184, 2009 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 694 Issue: 14
  • Publication Date: 2009
  • Doi Number: 10.1016/j.jorganchem.2009.02.023
  • Journal Name: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Page Numbers: pp.2179-2184
  • Keywords: Palladacycles, Imidazolinium salts, N-heterocyclic carbenes, Ring opening, Hydrolysis, HETEROCYCLIC-CARBENE COMPLEXES, CROSS-COUPLING REACTIONS, CATALYTIC-ACTIVITY, PALLADIUM, LIGANDS, POLYIMIDES, REACTIVITY, STABILITY, PHOSPHINE, ADDUCTS
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

Deprotonation of 1,3-diorganyl imidazolinium salts, 1, with N,C-type palladacyclic acetate dimer 2 afforded novel NHC coordinated complexes 3 along with ring opening hydrolysis products 4, which may coordinate to palladium center via NH group to give 5a. The hydrolysis necessitates the study of NHC complex formation in anhydrous media. The new compounds were characterized by spectroscopic methods and three of them (3c, 4c, 5a) by X-ray single-crystal diffraction studies. (C) 2009 Elsevier B. V. All rights reserved.