Synthesis and characterization of new air stable primary amido substituted diborane(4) derivatives

FIRINCI E., SÖYLEYİCİ H. C., GİZİROĞLU E., Temel E., Buyukgungor O., Sahin Y.

POLYHEDRON, vol.29, no.5, pp.1465-1468, 2010 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 29 Issue: 5
  • Publication Date: 2010
  • Doi Number: 10.1016/j.poly.2010.01.031
  • Journal Name: POLYHEDRON
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Page Numbers: pp.1465-1468
  • Keywords: Boranes, Diborane(4), Air stable, X-ray structures, CHEMISTRY, BORON, COMPLEXES
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

Three new diborane(4) derivatives, 1,2-bis(2,4,6-trimethylanilide)-1,2-bis(dimethyamido)diborane(4) (1), 1,2-bis(2,4,6-trimethylanilide)-1,2-bis(duryl)diborane(4) (2) and 1,2-bis(anilide)-1,2-bis(duryl)diborane(4) (3), have been synthesized and characterized by means of elemental analysis, IR, H-1, DC and B-11 NMR spectroscopy. Additionally, the structures of compounds 1 and 2 have been determined by the single crystal X-ray diffraction technique. The compounds 1 and 2 crystallize in the monoclinic P21/c space group. All of the compounds were found to be air stable. (C) 2010 Elsevier Ltd. All rights reserved.