2-[(E)-(4-Methylphenyl)iminomethyl]-6-(morpholin-4-ylmethyl)phenol
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.67, 2011 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 67
- Publication Date: 2011
- Doi Number: 10.1107/s1600536810052311
- Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Open Archive Collection: AVESIS Open Access Collection
- Ondokuz Mayıs University Affiliated: Yes
Abstract
In the title compound, C19H22N2O2, the morpholine ring adopts an almost perfect normal chair conformation with puckering parameters Q(T), theta and phi of 0.5642 (18) angstrom, 177.32 (17) and phi = 10 (4)degrees, respectively. The two benzene rings make a dihedral angle of 42.67 (8)degrees with each other. An intramolecular O-H center dot center dot center dot N hydrogen bond helps to stabilize the molecular conformation. Aromatic C-H center dot center dot center dot pi interactions and pi-pi stacking interactions [centroid-centroid distance = 3.6155 (15) angstrom] between the benzene rings contribute to the stabilization of the crystal structure.