EXPERIMENTAL AND THEORETICAL (DFT) STUDIES OF POLY[OCTA-mu(3)-ACESULFAMATO-O,O:N,O ';O ',N:O,O-TETRAAQUATETRABARIUM(II)] AND POLY[OCTA-mu(3)-ACESULFAMATO-O,O:N,O ';O ',N:O,O-TETRAAQUATETRASTRONTIUM(II)] COMPLEXES

İçbudak H., Demirtas G., DEGE N.

MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING, cilt.34, sa.1, ss.105-114, 2015 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 34 Sayı: 1
  • Basım Tarihi: 2015
  • Dergi Adı: MACEDONIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
  • Sayfa Sayıları: ss.105-114
  • Anahtar Kelimeler: acesulfamato ligand, barium(II) complex, strontium(II) complex, density functional theory, SECONDARY BUILDING UNITS, STRUCTURAL-CHARACTERIZATION, CRYSTAL-STRUCTURE, IONIC LIQUIDS, GAS SORPTION, ACESULFAMATE
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

Two new one-dimensional coordination polymers of barium(II) and strontium(II)-acesulfamato complexes such as [Ba(C4H4NO4S)(2)(H2O)](n) (1) and [Sr(C4H4NO4S)(2)(H2O)](n) (2) have been synthesized and their molecular structures were identified by X-ray diffraction technique. Both barium(II) and strontium(II) complexes crystallize in the centrosymmetric monoclinic space group P12(1)/c1 and barium(II) and strontium(II) ions, which are surrounded by O- and N-atoms, have the coordination number of nine. Each complex forms a structure like a polymer extending parallel to the a-axis. The molecular structures of those complexes were stabilized by O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds.