Solid-state Electrochemical Sensor Based on a Cross-linked Copper(II)-doped Copolymer and Carbon Nanotube Material for Selective and Sensitive Detection of Monohydrogen Phosphate

Topcu C., Çoldur F., Çağlar B., Özdokur K. V., Çubuk O.

Electroanalysis, vol.34, no.3, pp.474-484, 2022 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 34 Issue: 3
  • Publication Date: 2022
  • Doi Number: 10.1002/elan.202100340
  • Journal Name: Electroanalysis
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
  • Page Numbers: pp.474-484
  • Keywords: Monohydrogen phosphate sensor, Potentiometric monohydrogen phosphate determination, Solid-state sensor, Copper(II) doped-copolymer, Carbon nanotube, Water analysis
  • Ondokuz Mayıs University Affiliated: No

Abstract

© 2021 Wiley-VCH GmbH.A novel solid-state electrochemical sensor based on a newly synthesized cross-linked copper(II) doped-copolymer and carbon nanotube material was developed for the direct determination of monohydrogen phosphate ions (HPO42−). The synthesized copolymers were characterized by FTIR, XPS, TG/DTG-DTA and SEM techniques. The sensor had a Nernstian slope:-30.7±0.4 mV/decade, linear concentrations range: 1.0×10−6 - 1.0×10−1 M, detection limit: 6.5×10−7 M, response time: 4 s and life time: 17 weeks. The sensor displayed constant potentials in the pH range 7.0-9.5. The sensor was successfully used as an indicator electrode in potentiometric titration and the direct determination of HPO42− in water samples.