Synthesis, thermal, spectroscopic and structural properties of di(aqua)bis(N,N'-dimethylethylenediamine-k(2)N,N')copper(II) acesulfamate

Icbudak H., Uyanik A., Bulut A., Arici C., Uelkue D.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, vol.222, no.8, pp.432-436, 2007 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 222 Issue: 8
  • Publication Date: 2007
  • Doi Number: 10.1524/zkri.2007.222.8.432
  • Journal Name: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
  • Page Numbers: pp.432-436
  • Keywords: acesulfamate, N,N'-dimethylethylenediamine, mass spectrometry, thermal analysis, single crystal structure analysis, X-ray diffraction, NICKEL(II) COMPLEXES, CRYSTAL-STRUCTURES, SOLID-STATE, COPPER(II), N,N-DIETHYLETHYLENEDIAMINE, THERMOCHROMISM, CO(II), NI(II), LIGAND
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

The complex [Cu(C4H12N2)(2)(H2O)(2)](2+) [(C4H4NO4S)(-)](2), which is the first structurally characterized complex with acesulfamate as the counter anion, has been synthesized and characterized by elemental analyses, magnetic and conductivity measurements, UV/vis, FT-IR and mass spectra. The thermal behaviour of the complexes was studied by simultaneous TG, DTG and DTA methods in a static air atmosphere. In the crystal structure, the copper cation, lying on a crystallographic centre of symmetry, adopts an elongated octahedral trans-[CuN4O2] coordination geometry, with long axial Cu-O(aqua) bond length and short equatorial Cu-N bonds, of 2.479(2), 2.035(2) and 2.051(2) angstrom, respectively. The coordinated water molecules together with the amine part of the dimethylethylene-diamine molecule link the acesulfamate ions to the metal complex via intermolecular hydrogen bonds.