Synthesis and characterization of Co(II), Ni(II) and Cu(II) complexes of 3-[(2,4-dinitrophenyl)hydrazono]butane-2-one oxime


Bati H., Taş M., Davran C.

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, vol.51, no.5, pp.728-731, 2006 (SCI-Expanded, Scopus)

Abstract

In this study, Co(II), Ni(II) and Cu(II) complexes of 3-[(2,4-dinitrophenyl)hydrazono]butane-2-one oxime were synthesized and characterized by means of IR, UV-Vis, H-1 NMR spectroscopic techniques, magnetic measurements, and elemental analyses. The ligand (HL) behaves as a monoanionic bidentate ligand coordinating via azomethine nitrogen of the hydrazone and the oxime oxygen with the displacement of a hydrogen atom from the oxime group.