Iron(III) complex of a tridentate NNN type ligand: synthesis, X-ray structure, thermal analysis and voltammetric studies

HOPA Ç., ALKAN M., Kazak C., Arslan N. B., Kurtaran R.

TRANSITION METAL CHEMISTRY, vol.34, no.4, pp.403-407, 2009 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 34 Issue: 4
  • Publication Date: 2009
  • Doi Number: 10.1007/s11243-009-9209-9
  • Journal Name: TRANSITION METAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.403-407
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

A mononuclear iron(III) complex with 2,6-bis(3,4,5-trimethyl-N-pyrazolyl)pyridine (btmpp) has been synthesized, and characterized by X-ray crystallography, IR, UV-Vis and TGA-DTA methods. The Fe(III/II) couple was characterized by way of cyclic voltammetry using DMF solvent, where the complex was observed to have an irreversible behaviour.