Synthesis, crystal structure, spectral and thermal characterization of bis(o-vanillinato)-triethylenglycoldiiminecopper(II) and bis[(R)-(-)-hydroxymethylpropylimine o-vanillinato]copper(II)

Arslan F., ODABAŞOĞLU M., Olmez H., Buyukgungor O.

POLYHEDRON, vol.28, no.14, pp.2943-2948, 2009 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 28 Issue: 14
  • Publication Date: 2009
  • Doi Number: 10.1016/j.poly.2009.06.092
  • Journal Name: POLYHEDRON
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Page Numbers: pp.2943-2948
  • Keywords: Schiff base complex, Thermal decomposition, Copper complex, o-Vanillin complex, SCHIFF-BASE LIGANDS, X-RAY STRUCTURES, COPPER(II) COMPLEXES, METAL-COMPLEXES, THIOSEMICARBAZONE, MANGANESE(II), CHROMIUM(III), CADMIUM(II), NICKEL(II), COBALT(II)
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

The novel complexes bis(o-vanillinato)-triethylenglycoldiiminecopper(II) (1) and bis[(R)-(-)-hydroxymethylpropylimine o-vanillinato]copper(II) (2) have been synthesized and characterized by elemental analysis, magnetic susceptibility, spectral methods (UV-Vis and FT-IR), simultaneous TG, DTA techniques and X-ray diffraction. The crystal structure of (1) determined that the Cu atom is coordinated by two imine N atoms and two phenol O atoms from the Schiff base ligand in a slightly distorted square-planar coordination. The o-vanillinato ligands moieties of the molecule are in a trans configuration and the dihedral angle between the aromatic ring planes is 43.97(14)degrees. Compound (2) crystallizes in the triclinic space group P (1) over bar with unit-cell parameters a = 8.054(7), b = 8.684(7), c = 10.258(8) angstrom, alpha = 79.452(6)degrees, beta = 70.454(6)degrees, gamma = 65.427(6)degrees and Z = 1. The crystal structure of (2) has indicated that the complex is slightly distorted square planar and is chelated by the two imine N atoms and two phenol O atoms from the Schiff base ligand. The o-vanillinato ligands moieties of (2) are in a trans configuration and the torsion angle between the aromatic ring planes is 60.5(3)degrees. The crystal packing involves both hydrogen-bonding and C-H center dot center dot center dot pi interactions. Thermal analyses showed that the title compounds decompose in two stages over the temperature range 20-1000 degrees C in a static air atmosphere. (C) 2009 Elsevier Ltd. All rights reserved.