Crystal structure of (E)-2,6-di-tert-butyl-4-{[2-(2,4-dinitrophenyl) hydrazinylidene] methyl} phenol

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Faizi M. S. H., DEGE N., Haque A., Kalibabchuk V. A., Çemberci M.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.73, ss.96-104, 2017 (ESCI) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 73
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1107/s2056989016020107
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.96-104
  • Anahtar Kelimeler: crystal structure, hydrazine, dinitrobenzene, di-tert-butylphenol, 3,5-di-tert-butyl-4-hydroxybenzaldehyde, 2,4-dinitrophenylhydrazine, hydrogen bonding, BIOLOGICAL-ACTIVITY
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The essential part (including all the non-hydrogen atoms except two methyl carbons) of the molecule of the title compound, C21H26N4O5, lies on a mirror plane, which bisects the t-butyl groups. The conformation of the C N bond of this Schiff base compound is E, and there is an intramolecular N-H center dot center dot center dot O hydrogen bond present, forming an S(6) ring motif. In the crystal, molecules are linked via O-H center dot center dot center dot O hydrogen bonds, forming zigzag chains propagating along the a-axis direction. There are no other significant intermolecular contacts present.