A novel 1D coordination polymer [Pb(phen)(mu-N-3)(mu-NO3)](n) with the first Pb-2-(mu-N-3)(2) unit (phen=1,10-phenanthroline)

Marandi F., Mirtamizdoust B., Soudi A. A., YILMAZ V. T., Kazak C.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol.632, no.15, pp.2380-2382, 2006 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 632 Issue: 15
  • Publication Date: 2006
  • Doi Number: 10.1002/zaac.200600184
  • Journal Name: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.2380-2382
  • Keywords: lead, crystal structure, pi-pi stacking interaction, LIGANDS LEAD(II) COMPLEX, CRYSTAL-STRUCTURE, MOLECULAR-STRUCTURE, LONE-PAIR, COMPOUND
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

A novel ID polymeric lead(II) complex containing the first Pb-2-(mu-N-3)(2) motif, [Pb(phen)(mu-N-3)(mu-NO3)](n) (phen = 1,10-phenanthroline), has been synthesized and characterized. The single-crystal X-ray data showed the coordination number of Pb2+ ions to be eight (PbN4O4) with the Pb2+ ions having "stereo-chemically active" electron lone pairs; the coordination sphere is hemidirected. The chains interact with each other via pi-pi interactions to create a 3D framework.