Crystal structure and Hirshfeld surface analysis of 2-phenyl-1H-phenanthro[9,10-d]imidazol-3-ium benzoate

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Ahmed R., Doğan O. E., Ali F., Ahmad M., Ahmed A., DEGE N., ...Daha Fazla

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.76, ss.724-733, 2020 (ESCI) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 76
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1107/s2056989020005344
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.724-733
  • Anahtar Kelimeler: crystal structure, 2-phenyl-1-H-phenanthro[9,10-d]imidazole, hydrogen bonding, pi-pi interactions, FUSED N-HETEROACENE
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

In the title compound, C21H15N2+center dot C7H5O2-, 2-phenyl-1H-phenanthro[9,10-d]imidazole and benzoic acid form an ion pair complex. The system is consolidated by hydrogen bonds along with pi-pi interactions and N-H center dot center dot center dot pi interactions between the constituent units. For a better understanding of the crystal structure and intermolecular interactions, a Hirshfeld surface analysis was performed.