Synthesis, Characterization, Crystal Structure, Thermal Behavior, and Biological Activity of a New Heterotrinuclear Complex: [(NiL(NCS)(H2O))(2)Cd(DMF)(2)]

YARDAN A., Karahan A., Arslan N. B., HOPA Ç., GÖKMEN M., Kazak C., ...More

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, vol.45, no.8, pp.1224-1233, 2015 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 45 Issue: 8
  • Publication Date: 2015
  • Doi Number: 10.1080/15533174.2013.862679
  • Journal Name: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1224-1233
  • Keywords: Schiff base ligands, hetero trinuclear complexes, thermal analysis, single crystal XRD, biological activity, SCHIFF-BASE COMPLEXES, MOLECULE-MAGNET BEHAVIOR, LIGAND, NICKEL(II), NANOSTRUCTURES, DECOMPOSITION, COPPER(II), COBALT(II), BRIDGES, ZN(II)
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

A new trinuclear heterometallic nickel(II)-cadmium(II)-nickel(II) complex, [(NiL(NCS)(H2O))(2)Cd(DMF)(2)] (DMF: dimethylformamide) (1), has been synthesized by using NiL as the so-called metallo ligand where H2L = N,N-bis(salicylidene)-1,3-diaminopropane, cadmium nitrate, and amonium thiocyanate. The title complex was characterized by various methods including elemental analyses, IR, H-1-NMR, C-13-NMR, TG-DTA, and X-ray diffraction techniques. The complex crystallizes in monoclinic space group P2(1/c), with unit cell dimensions a = 10.6217(3), b = 13.3487(4), c = 16.0043(4) angstrom, = 93.823(2)degrees. The complex was screened for antimicrobial activities by the disc diffusion using DMF as solvent. The minimum inhibitory concentration values were calculated.