1,3-Bis(4-methylphenyl)triazene, 1-(4-chlorophenyl)-3-(4-fluorophenyl)triazene and 1-(4-fluorophenyl)3-(4-methylphenyl)triazene

Karadayi, Nevzat; Cakmak, S; Odabasoglu, M; Buyukgungor, O

doi:10.1107/s0108270105004373

1,3-Bis(4-methylphenyl)triazene, 1-(4-chlorophenyl)-3-(4-fluorophenyl)triazene and 1-(4-fluorophenyl)3-(4-methylphenyl)triazene

Karadayi N., Cakmak S., Odabasoglu M., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, cilt.61, 2005 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 61
Basım Tarihi: 2005
Doi Numarası: 10.1107/s0108270105004373
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The title 4,4'-disubstituted diphenyl-1,3-triazines, C14H15N3, (I), C12H9ClFN3, (II), and C13H12FN3, (III), each contain a triazene group (-N=N-NH-) having an extended conformation. The dihedral angles between the two benzene rings in (1), (II) and (III) are 4.3, 3.4 and 6.5 degrees, respectively. The molecules are almost entirely planar, with maximum deviations from the mean planes of 0.1087 (2), -0.1072 (7) and 0.1401 (3) angstrom, respectively. In each compound, the molecules are linked by N-H center dot center dot center dot N hydrogen bonds to form chains and pack similarly in the crystal structures.