Butylamine-resadiye bentonite composite characterization

Koksal E., Afsin B., Tabak A., Caglar B.

SPECTROSCOPY LETTERS, cilt.53, sa.10, ss.745-750, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 53 Sayı: 10
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1080/00387010.2020.1832530
  • Dergi Adı: SPECTROSCOPY LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Analytical Abstracts, Applied Science & Technology Source, Biotechnology Research Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, INSPEC, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.745-750
  • Anahtar Kelimeler: Bentonite, butylamine, composite, hydrogen bonding, incorporation, PILLARED MONTMORILLONITE, CATIONIC SURFACTANTS, ORGANIC-COMPOUNDS, PARTICLE-SIZE, ADSORPTION, INTERCALATION, CLAYS, SORPTION, ACIDITY, MECHANISM
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The acid activation process increased the specific surface area of raw Resadiye bentonite (33.5 m(2)/g) by similar to 4-fold whereas the interaction with n-butylamine caused a surface area reduction of acid-activated bentonite by 40% along with the broadening of the Si-O stretching peak at 1041 cm(-1)and the decrease of the d(001)value from 14.5 to 13.5 angstrom. The thermal analysis data confirmed the stability of the mesoporous n-butylamine/acid-activated bentonite composite up to 499 degrees C which was followed by the cleavage of the interlayer n-butylamine species between 500 and 700 degrees C.