New cyano bridged heteropolynuclear Cu(II) and Cd(II)-tetracyanopalladate(II) polymeric complexes with 2-methylimidazole ligand

Kurkcuouglu G. S., Gor K., Buyukgungor O.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, vol.124, pp.588-594, 2014 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 124
  • Publication Date: 2014
  • Doi Number: 10.1016/j.saa.2014.01.049
  • Journal Name: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.588-594
  • Keywords: Cyano-bridging complex, Tetracyanopalladate(II) complex, 2-Methylimidazole complex, FT-IR and Raman spectra, Thermal analyses, Crystal structure, CRYSTAL-STRUCTURES, THERMAL ANALYSES, COORDINATION POLYMERS, MAGNETIC-PROPERTIES, IR-SPECTRA, TETRACYANOPALLADATE(II), 2D, 1-ETHYLIMIDAZOLE, CADMIUM(II), FRAMEWORK
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

New cyano-bridged heteronuclear polymeric complexes, [M(mim)(2)Pd(CN)(4)](n) (M = Cu(II) (1) or Cd(II) (2); mim = 2-methylmidazole), have been synthesized and characterized by elemental, thermal, FT-IR and Raman spectral analyses. The crystal structure of complex 1 has been determined by single crystal X-ray diffraction technique. The crystallographic analysis reveals that it crystallizes in the monoclinic system, space group P2(1)/c. The Pd(II) atom is coordinated by four cyano ligands, while Cu(II) atom is also surrounded by the two mim and two cyano ligands. The structure of 1 is formed by infinite 2,2-TT type chains of the [-Cu(mim)(2)-NC-Pd(CN)(2)-CN-](n) composition; these are interlinked by hydrogen bonds (HBs) leading to two-dimensional patterns. FT-IR and Raman spectral data indicate the presence of bridging cyano ligands in the structures of the complexes. (C) 2014 Elsevier B.V. All rights reserved.