An EPR study ofCu(2+) ions in [Zn(picol)(2)(H2O)(2)]center dot 2H(2)O single crystals

Karabulut B., Duezguen F., Keser C., Heren Z.

PHYSICA B-CONDENSED MATTER, vol.396, no.1-2, pp.8-11, 2007 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 396 Issue: 1-2
  • Publication Date: 2007
  • Doi Number: 10.1016/j.physb.2007.01.023
  • Journal Name: PHYSICA B-CONDENSED MATTER
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.8-11
  • Keywords: EPR, Cu, spin-Hamiltonian parameters, doping, CU2+, ESR
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

Electron paramagnetic resonance spectra of Cu2+ -doped [Zn(picol)(2)(H2O)(2)].2H(2)O (C12H18N2O8Zn) single crystals which were taken at room temperature are discussed. It was found from the analysis of the EPR data that the Cu2+ ions substitute for magnetically inequivalent Zn2+ ions. Two magnetically inequivalent sites for Cu2+ were observed. The spin Hamiltonian parameters were determined and thus, the ground state wave functions of Cu2+ ions in two sites were constructed. (c) 2007 Published by Elsevier B.V.