Molecular structure and EPR spectral studies of trans-Bis(perchlorato-kappa O)tetrakis(1-vinyl-1Himidazole-kappa N-3)copper(II)
CHEMICAL PHYSICS LETTERS, cilt.592, ss.59-63, 2014 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 592
- Basım Tarihi: 2014
- Doi Numarası: 10.1016/j.cplett.2013.12.007
- Dergi Adı: CHEMICAL PHYSICS LETTERS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.59-63
- Ondokuz Mayıs Üniversitesi Adresli: Evet
Özet
A new copper(II) complex of 1-vinylimidazole (1-Vim) and perchlorate has been synthesized and structurally characterized. The molecular structure of the complex exhibits six coordination with a distorted octahedron geometry. The complex crystallizes in triclinic system with the space group P-1. The magnetic environment of the title complex has been identified by electron paramagnetic resonance (EPR) technique. Detailed investigations of the EPR spectra show that the local symmetry of the Cu2+ ions is rhombic. Principal values of g and hyperfine tensors were determined and the ground state wave function of Cu2+ ions was obtained using EPR parameters. (C) 2013 Elsevier B.V. All rights reserved.