Synthesis, crystal structure and spectroscopic studies of a mixed ligand copper (II) complex: trans-bis(succinimidato)-bis(benzylamino)Cu(II)

Taş M., Saracoglu H., Bati H., Caliskan N., Buyukgungor O.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol.61, no.8, pp.979-982, 2006 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 61 Issue: 8
  • Publication Date: 2006
  • Journal Name: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.979-982
  • Keywords: succinimide, succinimidato, mixed ligand complex, COORDINATION GEOMETRY
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

The molecules of the title compound, [Cu(C11H13N2O2)(2)], lie across centres of inversion in space group P2(1)/c and are linked by intermolecular N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds. The central Cu atom has a slightly distorted square-planar coordination comprised of four N atoms. Cu-N bond distances are 1.975(2) and 2.020(2) angstrom. The interplanar angle between the phenyl and succinimidato ring is 87.34(10)degrees.