Synthesis, characterization, crystal structure and thermal analysis of a copper(II) mononuclear compound with 2,6-bis(3,5-dimethyl-N-pyrazolyl) pyridine (bdmpp) and selenocyanate as ligands

Kurtaran R., Namli H., Kazak C., Turhan O., ATAKOL O.

JOURNAL OF COORDINATION CHEMISTRY, vol.60, no.20, pp.2133-2138, 2007 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 60 Issue: 20
  • Publication Date: 2007
  • Doi Number: 10.1080/00958970701340511
  • Journal Name: JOURNAL OF COORDINATION CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.2133-2138
  • Keywords: pyrazolyl complexes, selenocyanate, trigonal-bipyramidal Cu(II) complexes, thermal analysis, MAGNETIC-PROPERTIES, TERPYRIDINE ANALOGS, COMPLEXES, COORDINATION, N-3(-), END
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

A single crystal of the copper(II) compound, [Cu(bdmpp)(SeCN)(2)], 2, was obtained and its crystal structure was determined by X-ray diffraction methods. The complex was characterized by elemental, thermal and FTIR analysis. The FTIR analysis of the complex clearly shows the SeCN peaks at 2096 and 2061 cm(-1) which did not exist in the free organic ligand ( bdmpp). X-ray analysis showed that 2 crystallized in the monoclinic space group P2(1)/c. Cu(II) has a distorted trigonal bipyramidal coordination involving three N atoms from the ligand and two N atoms from the selenocyanate group.