2-[(<i>E</i>)-2-Hydroxy-5-(trifluoromethoxy)benzylideneamino]-4-methylphenol
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.67, 2011 (SCI-Expanded)
- Publication Type: Article / Article
- Volume: 67
- Publication Date: 2011
- Doi Number: 10.1107/s1600536810050579
- Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
- Open Archive Collection: AVESIS Open Access Collection
- Ondokuz Mayıs University Affiliated: Yes
Abstract
The title compound, C15H12F3NO3, is a Schiff base which adopts the cis-quinoid form in the solid state. The dihedral angle between the least-squares planes of the benzene rings being 3.6 (1)degrees. The F atoms of the -CF3 group are disordered over two sets of sites with refined occupancies of 0.61 (5) and 0.39 (5). An intramolecular N-H center dot center dot center dot O hydrogen bond occurs. The crystal structure is stabilized by intermolecular O-H center dot center dot center dot O hydrogen bonds.