(Z)-2-[(E)-2-(1-Benzothiophen-3-yl-methylidene)hydrazin-1-ylidene]-1,2-diphenylethanone

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Pekdemir M., Isik S., Gumus S., Ağar E., SOYLU M. S.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.68, pp.2579-2587, 2012 (ESCI)

• Publication Type: Article / Article
• Volume: 68
• Publication Date: 2012
• Doi Number: 10.1107/s1600536812030978
• Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
• Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
• Page Numbers: pp.2579-2587
• Ondokuz Mayıs University Affiliated: Yes

Abstract

The title compound, C23H16N2OS, is not planar, the phenyl ring of the benzoyl group making a dihedral of 77.61 (7)degrees with the benzothiophene system ring. The benzothiophene system and the remaining phenyl ring make an angle of 12.71 (13)degrees. The conformation around the imine functions is E for the C=N bond towards the benzothiophene system and Z for the C=N bond towards the benzoyl group. The packing of the molecules shows C-H center dot center dot center dot pi interactions. A weak intramolecular C-H center dot center dot center dot N bond also occurs.